生态减污袋去除模拟污水中氨氮及磷的效果试验

研究利用砂土与粘土混合制成的生态减污袋对于模拟污水中氨氮及磷的去除效果。研究发现砂土与粘土比例为1∶1的减污袋对于高浓度模拟污水中氨氮和磷的去除率分别达到73%和63%;而砂土与粘土比例为10∶1的减污袋对于低浓度模拟污水中磷的去除率最高达到49%。对于高浓度污水,采用砂土与粘土比例为1∶1的生态减污袋能取得最好的除磷去氮效果;而对于低浓度污水,采用砂土与粘土比例为10∶1的生态减污袋除磷去氮效果较好并且成本相对较低。     

Degradation of polycyclic aromatic hydrocarbons by Pseudomonas sp. JM2 isolated from active sewage sludge of chemical plant

It is important to screen strains that can decompose polycyclic aromatic hydrocarbons (PAHs) completely and rapidly with good adaptability for bioremediation in a local area. A bacterial strain JM2, which uses phenanthrene as its sole carbon source, was isolated from the active sewage sludge from a chemical plant in Jilin, China and identified as Pseudomonas based on 16S rDNA gene sequence analysis. Although the optimal growth conditions were determined to be pH 6.0 and 37℃, JM2 showed a broad pH and temperature profile. At pH 4.5 and 9.3, JM2 could degrade more than 40% of fluorene and phenanthrene (50 mg/L each) within 4 days. In addition, when the temperature was as low as 4℃, JM2 could degrade up to 24% fluorene and 12% phenanthrene. This showed the potential for JM2 to be applied in bioremediation over winter or in cold regions. Moreover, a nutrient augmentation study showed that adding formate into media could promote PAH degradation, while the supplement of salicylate had an inhibitive effect. Furthermore, in a metabolic pathway study, salicylate, phthalic acid, and 9-fluorenone were detected during the degradation of fluorene or phenanthrene. In conclusion, Pseudomonas sp. JM2 is a high performance strain in the degradation of fluorene and phenanthrene under extreme pH and temperature conditions. It might be useful in the bioremediation of PAHs.     

Occurrence of selected aliphatic amines in source water of major cities in China

The formation of toxic nitrogenous disinfection byproducts (N-DBPs), such as nitrosamines, halonitromethanes and haloacetonitriles, from reactions between chlorine/chloramine and dissolved organic nitrogen in drinking water has caused great concern with regarding public health. This study revealed the occurrence of 17 aliphatic amines, some of which have been confirmed to be the precursors of N-DBPs, in source water across China. A sensitive method based on benzenesulfonyl chloride derivatization and liquid-liquid extraction followed by GC-MS analysis was established for the simultaneous analysis of the selected amines in aqueous samples. In total, 37 source water samples from the capital cities of 20 provinces were collected for the survey. Among the 17 amines, 14 were detected with an average frequency of detection of 36%. The most relevant amines in terms of frequency and maximum concentrations detected were dimethylamine (100%, 24.82 μg/L), methylamine (78%, 0.92 μg/L), N-methylethylamine (70%, 8.84 μg/L), propylamine (59%, 10.69 μg/L), diethylamine (54%, 3.76 μg/L), N-methylbutylamine (35%, 3.07 μg/L), N-ethylpropylamine (35%, 0.52 μg/L), and piperidine (32%, 2.35 μg/L). This is the first large scale survey of the aliphatic amines occurrence in source water in the world. The wide presence of nitrosamine precursors like dimethylamine, N-methylethylamine and diethylamine, and the precursors of haloacetonitriles and halonitromethanes like methylamine and propylamine suggests that better source water management is required to ensure the safety of drinking water.     

Rapid decolorization of Acid Orange II aqueous solution by amorphous zero-valent iron

Some problems including low treatment capacity, agglomeration and clogging phenomena, and short working life, limit the application of pre-treatment methods involving zero-valent iron (ZVI). In this article, ZVI was frozen in an amorphous state through a melt-spinning technique, and the decolorization effect of amorphous ZVI on Acid Orange II solution was investigated under varied conditions of experimental variables such as reaction temperature, ribbon dosage, and initial pH. Batch experiments suggested that the decolorization rate was enhanced with the increase of reaction temperature and ribbon dosage, but decreased with increasing initial solution pH. Kinetic analyses indicated that the decolorization process followed a first order exponential kinetic model, and the surface-normalized decolorization rate could reach 2.09 L/(m². min) at room temperature, which was about ten times larger than any previously reported under similar conditions. Recycling experiments also proved that the ribbons could be reused at least four times without obvious decay of decolorization rate and efficiency. This study suggests a tremendous application potential for amorphous ZVI in remediation of groundwater or wastewater contaminated with azo dyes.     

耕地资源非市场价值评价方法的研究进展与述评

论文系统梳理了国内外耕地资源非市场价值评价方法的研究进展,指明了今后该领域研究的努力方向。研究结果表明:国内评价耕地资源非市场价值的方法主要是CVM,研究方法单一,缺少同时运用其他非市场价值评价方法来对CVM的研究进行比较的案例,从而无法清晰辨识CVM的缺陷,并对其加以改进;而且,CVM方法本身存在一些不足,大多数CVM的应用尚停留在实施CVM实验并报告结果的初级阶段,对CVM的有效性与可靠性方面的相关研究不够。国外非市场价值评价方法表现出两个特点:一是研究方法不断拓展,Mixed Logit逐步得到应用;二是研究方法不断深化,对CVM的研究从调研内容与结果的报告,向检验结果的有效性、可靠性方向转变,进而转向CVM的经济学理论的探讨和研究;对CVM与预期不相符合的原因进行深入研究;对问卷的设计进行深入研究;并将非市场价值评价模型和方法与空间分析相结合。在此基础上,建议将CE模型引入中国的耕地资源非市场价值评价研究;加强耕地资源非市场价值的空间分异特征与分异规律,以及耕地资源非市场价值形成的空间分异机理和动态演变规律的研究;尝试调查问卷设计中的可视化研究。     

环氧化PVA载体固定漆酶的最佳工艺条件研究

在T=35℃,HAc-NaAc缓冲溶液pH为4的条件下,用环氧化PVA载体对漆酶进行固定化,固定后酶活为游离酶活的95%。用该固定化漆酶处理制浆造纸废水,反复使用6次后,酶活仍保持为初始酶活的45%,且每次COD去除率在40%以上,处理后的废水BOD增大了50%,废水可生化性得到很大提高。     

基于传声器阵列的声源定位技术的应用

基于传声器阵列的声源定位技术中的两个主要方法,STSF和Beamforming声源定位技术两者的实现方法不同。通过对STSF和Beamforming声源定位技术的推导,给出了两种测量技术适用的频率范围和空间范围,从理论上对其应用范围的差异进行了说明,并提出在实际测量中如何选择合适的声源定位方法。结合两种测量技术的特点,提出声源定位技术下一阶段研究的重点。     

热媒炉导热油的清洗与更换

对热媒炉导热油系统结垢的原因进行分析.介绍了热媒炉导热油系统清洗的方法,比较各种清洗方法的异同.对清洗更换导热油时的注意事项进行说明,对试运情况及取样化验数据进行分析.     

Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extraction and gas chromatography-mass spectrometry

In this paper, a method using solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) was developed to simultaneously analyze five taste and odor compounds in surface water, i.e., 2-methylisoborneol (2-MIB), 2,4,6-trichloroanisole (TCA), 2-isopropyl-3-methoxy pyrazine (IPMP), 2-isobutyl-3-methoxy pyrazine (IBMP), and trans-1,10-dimethyl-trans-9-decalol (geosmin, GSM). The mass spectrometry was operated in selective ion monitoring (SIM) mode. Three kinds of SPE columns and three eluting solvents were compared, the C18 column was chosen as optimum SPE column, and methanol was chosen as the optimum eluting solvent. It was found that the method showed good linearity in the range of 1–200 ng·L⁻¹ and gave detection limits of 0.5–1.5 ng·L⁻¹ for individual compounds. Good recoveries (93.5%–108%) and relative standard deviations (1.58%–7.31%) were also obtained. Additionally, concentrations of these taste and odor compounds in Jinan’s surface and drinking water were analyzed by applying this method, and the results showed that GSM and 2-MIB were the dominant taste and odor compounds in Jinan’s raw water.     

基于系统动力学的食品企业安全生产监管博弈研究

为了研究食品安全生产及监管的内在机理、影响因素及监管模式,采用演化博弈论方法建立了政府监管部门与食品企业之间的博弈模型,运用复制动态方程和系统动力学方法深入分析了食品安全生产中相关主体的决策选择。结果表明:食品企业在追求利益最大化的前提下须主动重视食品安全问题,食品企业的策略选择受安全生产投入成本、处罚成本和声誉收益的影响;政府监管部门的监管行为受监管成本、外部负效益及社会成本等多方因素的影响。因此,增大监管部门惩处力度、降低监管成本、完善社会公众监督机制、强化声誉效应是食品安全问题得以解决的有力保障。